A Sequential Pd-AAA/Cross-Metathesis/Cope Rearrangement Strategy for the Stereoselective Synthesis of Chiral Butenolides
نویسندگان
چکیده
منابع مشابه
Synthesis of 5,5-disubstituted butenolides based on a Pd-catalyzed gamma-arylation strategy.
Methods for the construction of quaternary carbon centers are of great interest to synthetic chemists due to their presence in natural products. Development of the Pd-catalyzed arylation of butenolides with high selectivity for the gamma-position allows for a facile construction of quaternary centers. The preparation of a wide variety of gamma-aryl butenolides containing a number of functional ...
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ژورنال
عنوان ژورنال: Organic Letters
سال: 2019
ISSN: 1523-7060,1523-7052
DOI: 10.1021/acs.orglett.9b00521